SOLAS™ silica gel for Chromatography

SOLAS™ MonoDense™ is a proprietary process for the industries first monodense fully porous silica particle for use in HPLC and UHPLC. Have you ever imaged fully porous silica particles using state of the art focused ion beam (FIB) milling techniques (normally utilised in microfabrication environments)? If you did you would find that the inside of traditional fully porous silica particles contains voids or holes. These voids can be up to an order of magnitude bigger than the pore size of the silica. These holes or voids cause mass transfer issues which can lead to peak broadening, peak tailing and ultimately losses in efficiency. By comparison the SOLAS™ MonoDense™ particles are monodense and contain a homogeneous pore structure which allows for the efficient transfer of analytes into and out of the silica pore structure, thereby leading to more efficient and effective chromatography. Additionally, the Glantreo particles represent a media that is easier to pack with a reduced failure rate in packing.

 

Typical Physical Properties

Purity0.9999
Parcticle Sizes1.9um, 3um
d90/d101.3
Pore Size100A
Pore Volume0.65 cm3g-1
Surface Area300 m2g-1
Carbon Coverage14%
Bonding Density2.4umol/m2
Reduced Plate Height<2.5

Product CodeParticle Size (µm)Pack Size (g)Chemistry
PFPP1.9100R-101.910Raw silica
PFPP1.9100R-501.950Raw silica
PFPP1.9100C18-101.910C18
PFPP1.9100C18-501.950C18
PFPP1.9100C4-101.910C4
PFPP1.9100C8-101.910C8
PFPP1.9100C8-501.950C8
PFPP1.9100C4-501.950C4
PFPP3.0100R-103.010Raw silica
PFPP3.0100R-503.050Raw silica
PFPP3.000C18-103.010C18
PFPP3.0100C18-503.050C18
PFPP3.000C4-103.010C4
PFPP3.0100C4-503.050C4
PFPP3.0100C8-103.010C8
PFPP3.0100C8-503.050C8

$200.00$2,650.00

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Citations using Glantreo's materials

Davide Barreca, Mark P. Copley, Andrew E. Graham, Justin D. Holmes, Michael A. Morris, Roberta Seraglia, Trevor R. Spalding, Eugenio Tondello, Methanolysis of styrene oxide catalysed by a highly efficient zirconium-doped mesoporous silica, Applied Catalysis A: General, Volume 304, 10 May 2006, Pages 14-20, ISSN 0926-860Xhttp://www.sciencedirect.com/science/article/pii/S0926860X06001013

Clifford A. Barnes, Andreas Elsaesser, Joanna Arkusz, Anna Smok, Jadwiga Palus, Anna Lesniak, Anna Salvati, John P. Hanrahan, Wim H. de Jong, Elzbieta Dziubaltowska, Maciej St?pnik, Konrad Rydzynski, George McKerr, Iseult Lynch, Kenneth A. Dawson and C. Vyvyan Howard, Reproducible Comet Assay of Amorphous Silica Nanoparticles Detects No Genotoxicity. Nano Letters, 2008, 8 (9), pp 3069–3074. doi: 10.1021/nl801661w http://pubs.acs.org/doi/abs/10.1021/nl801661w#citing

Iseult Lynch, Sara Linse, C Vyvyan Howard, Maciej Stepnik, Konrad Rydzynski, John Hanrahan, Wim de Jong, Dominique Langevin, Joachim Rädler, Wolfgang Parak, Yuri Volkov, Marek Radomski, Robert Thomas, Jacob Klein, Andrew A Barron, Colin Janssen, Fiona M Lyons, Francis Quinn, Bert Swennen, Peter Cuypers, Angela Duffy and Kenneth A Dawson, NANOINTERACT: A rational approach to the interaction between nanoscale materials and living matter, Journal of Physics: Conference Series Volume 170 Number 1.doi:10.1088/1742-6596/170/1/012040 http://iopscience.iop.org/1742-6596/170/1/012040/cites

Paul Delaney, Healy RM, Hanrahan JP, Gibson LT, Wenger JC, Morris MA, Holmes JD. Porous silica spheres as indoor air pollutant scavengers. Journal of Environmental Monitoring. 2010 Dec;12(12):2244-51. doi: 10.1039/c0em00226g.http://www.ncbi.nlm.nih.gov/pubmed/20941430

Ali H. Eltmimi, Leon Barron, Aran Rafferty, John P. Hanrahan,Olga Fedyanina, Ekaterina Nesterenko, Pavel N. Nesterenko, Brett Paull, Preparation, characterisation and modification of carbon-based monolithic rods for chromatographic applications, Journal of Separation Science, Volume 33, Issue 9, 10 March 2010, Pages 1231-1243, ISSN 1615-9306http://onlinelibrary.wiley.com/doi/10.1002/jssc.200900845/abstract

Paul Delaney, Colm McManamon, John P. Hanrahan, Mark P. Copley, Justin D. Holmes, Michael A. Morris, Development of chemically engineered porous metal oxides for phosphate removal, Journal of Hazardous Materials, Volume 185, Issue 1, 15 January 2011, Pages 382-391, doi:10.1016/j.molcatb.2014.06.007.http://www.sciencedirect.com/science/article/pii/S0304389410012069

Bashir Mustafa Mohamed, Navin Kumar Verma, Adriele Prina-Mello, Yvonne Williams, Anthony M Davies, Gabor Bakos, Laragh Tormey, Connla Edwards, John Hanrahan, Anna Salvati, Iseult Lynch, Kenneth Dawson, Dermot Kelleher,and Yuri Volkov, Activation of stress-related signalling pathway in human cells upon SiO2 nanoparticles exposure as an early indicator of cytotoxicity. Journal of Nanobiotechnology. 2011;9:29. doi:10.1186/1477-3155-9-29.http://www.jnanobiotechnology.com/content/9/1/29

Jesse O. Omamogho, John P. Hanrahan, Joe Tobin, Jeremy D. Glennon, Structural variation of solid core and thickness of porous shell of 1.7µm core–shell silica particles on chromatographic performance: Narrow bore columns, Journal of Chromatography A, Volume 1218, Issue 15, 15 April 2011, Pages 1942-1953, ISSN 0021-9673http://www.sciencedirect.com/science/article/pii/S0021967310016559

Laura J. Waters, Talib Hussain, Gareth Parkes, John P. Hanrahan, Joseph M. Tobin, Inclusion of fenofibrate in a series of mesoporous silicas using microwave irradiation, European Journal of Pharmaceutics and Biopharmaceutics, Volume 85, Issue 3, Part B, November 2013, Pages 936-941, ISSN 0939-6411http://www.sciencedirect.com/science/article/pii/S0939641113002816

Robert J. Ahern, John P. Hanrahan, Joseph M. Tobin, Katie B. Ryan, Abina M. Crean, Comparison of fenofibrate–mesoporous silica drug-loading processes for enhanced drug delivery, European Journal of Pharmaceutical Sciences, Volume 50, Issues 3–4, 20 November 2013, Pages 400-409, ISSN 0928-0987 http://www.sciencedirect.com/science/article/pii/S0928098713003400

Noreldeen H. Abdallah, Miriam Schlumpberger, Darragh A. Gaffney, John P. Hanrahan, Joseph M. Tobin, Edmond Magner, Comparison of mesoporous silicate supports for the immobilisation and activity of cytochrome c and lipase, Journal of Molecular Catalysis B: Enzymatic, Volume 108, October 2014, Pages 82-88, ISSN 1381-1177http://www.sciencedirect.com/science/article/pii/S1381117714001805

Darshan C. Patel, Zachary S. Breitbach, M. Farooq Wahab, Chandan L. Barhate, and Daniel W. Armstrong, Gone in Seconds: Praxis, Performance, and Peculiarities of Ultrafast Chiral Liquid Chromatography with Superficially Porous Particles, Analytical Chemistry, 27 May 2015, EPub ahead of print http://pubs.acs.org/doi/abs/10.1021/acs.analchem.5b00715

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